Search Results

Search Results - All

Refine Results
  1. 9901
    Cover Icon

    O território do concelho de Vila Verde, na Idade Média

    Publication
    journal article Portugal Open access
  2. 9902
    Cover Icon

    University students' sense of belonging to the home town: the role of residential mobility

    Publication
    In the study of young people's relationships with residential contexts, it is important to consider the role of developmental tasks (e.g. identity construction, academic and professional choices, etc.) in influencing Place Identity and Sense of Community. Residential mobility may represent an adaptive strategy for modifying some aspects of one's identity and a contributing factor to the development of autonomy from the family. Limited attention has been devoted to the study of the ways young people deal with their attachments to old and new places within this process. This study involved 203 university students, attending a large university in the North of Portugal. The aim was to investigate Place Identity (PI) and Sense of Community (SoC) related to the home town, and differences according to residential condition (native vs. temporary resident) and year of attendance (I vs. IV). Among students who moved, the role of motives (forced vs. voluntary) and of residential choices after graduation on PI and SoC were assessed. Results indicated that, among students who moved for academic reasons, SoC and PI related to the home town were lower and decreased from the first to the fourth year. SoC was higher among students who experienced the relocation as a forced choice. Students who anticipated to return to their home town after graduation had higher SoC and PI.
    journal article Portugal Restricted access
  3. 9903
    Cover Icon

    Fast mineralization and detoxification of amoxicillin and diclofenac by photocatalytic ozonation and application to an urban wastewater

    Publication
    The degradation of two organic pollutants (amoxicillin and diclofenac) in 0.1 mM aqueous solutions was studied by using advanced oxidation processes, namely ozonation, photolysis, photolytic ozonation, photocatalysis and photocatalytic ozonation. Diclofenac was degraded quickly under direct photolysis by artificial light (medium-pressure vapor arc, lambda(exc) > 300 nm), while amoxicillin remained very stable. In the presence of ozone, regardless of the type of process, complete degradation of both organic pollutants was observed in less than 20 min. Photolysis or ozonation on their own led to modest values of total organic carbon (TOC) removal (<6% or 41%, respectively in 180 min), while for photocatalysis (no ozone present) a significant fraction of nonoxidizable compounds remained in the treated water (similar to 15% after 180 min). In the case of photolytic ozonation, the kinetics of TOC removal was slow. In contrast, a relatively fast and complete mineralization of amoxicillin and diclofenac (30 and 120 min, respectively) was achieved when applying the photocatalytic ozonation process. The absence of toxicity of the treated waters was confirmed by growth inhibition assays using two different microorganisms, Escherichia coli and Staphylococcus aureus. Photocatalytic ozonation was also applied to an urban wastewater spiked with both amoxicillin and diclofenac. The parent pollutants were easily oxidized, but the TOC removal was only as much as 68%, mainly due to the persistent presence of oxamic acid in the treated sample. The same treatment allowed the effective degradation of a wide group of micropollutants (pesticides, pharmaceuticals, hormones and an industrial compound) detected in non-spiked urban wastewater.
    journal article Portugal Restricted access
  4. 9904
    Cover Icon

    Teorias da pintura

    Publication
    other Portugal Open access
  5. 9905
  6. 9906
    Cover Icon

    Extraction of Salicylic Acid Using Sustainable ATPSs and Respective Immobilization as API-IL at Small Pilot Scale

    Publication
    Active pharmaceutical ingredients (APIs), a class of emerging pollutants present in residual waters, are often found in hospital effluents and are known to pose profound consequences to aquatic environments, such as the feminization of fish, for which finding sustainable extractive methodologies for these chemical species is a must. Aqueous two-phase systems (ATPSs) constitute a liquid-liquid extraction technique with low environmental impact that often results in the use of a salting-out agent, such as tripotassium citrate (K(3)Citrate), to separate two otherwise miscible phases. To increase the solubility of the extracted active pharmaceutical ingredients while preserving their specific properties, one can immobilize them as novel ionic liquids (ILs), and these complex chemical compounds are known as active pharmaceutical ingredients-ionic liquids (API-ILs). In this work, salicylic acid (Sa), a pharmaceutical component with wide medical and industrial applications, was extracted in ATPSs and immobilized as cholinium salicylate. Specifically, the systems {ethyl lactate (1) + Na(3)Citrate or K(3)Citrate or Na(2)Tartrate or NaKTartrate or Na(2)Succinate (2) + water (3)} were used at 298.15 K and 0.1 MPa. To advance large-scale application, the extraction studies were performed at small pilot scale using 500 g of ATPS and with the compositions of the shortest and longest tie-lines, having obtained the largest partition coefficient (K = (10 +/- 2) x 10(1)) and extraction efficiency (E/ % = 98.2 +/- 0.7%) for the longest tie-lines of the ATPSs based on K(3)Citrate and Na(2)Tartrate, respectively. Then, the ATPS based on K(3)Citrate was used to immobilize salicylic acid, and the structures of the synthesized ionic liquids (cholinium salicylate and cholinium citrate) were validated using FTIR measurements and IR predictions from computational chemistry.
    journal article Portugal Restricted access
  7. 9907
  8. 9908
  9. 9909
  10. 9910
  11. 9911
  12. 9912
    Cover Icon

    Luís Filipe Castro Mendes (1950- )

    Publication
    other Portugal Open access
  13. 9913
  14. 9914
    Cover Icon

    A paracentese e as injecções iodadas na ascite

    Publication
    bachelor thesis Portugal Open access
  15. 9915
  16. 9916
    Cover Icon

    Rising of a single Taylor drop in a stagnant liquid-2D laminar flow and axisymmetry limits

    Publication
    A numerical (computational fluid dynamics (CFD)) study concerning the rise of individual liquid Taylor drops through vertical columns of stagnant heavier liquids is presented in this paper. CFD simulations were performed in Ansys Fluent, using its implementation of volume of fluid method, assuming the flow to be axisymmetric and laminar. Different physical conditions were tested, corresponding to different combinations of relevant dimensionless parameters and the numerical method was validated through experimental data available in the literature. The viscosity ratio between the lighter and the heavier liquid was within the range 0.01-40 and Eotvos number was between 8 and 30. Morton number was within the interval of 2.32 x 10(-6)-100. Froude number results were compared to data from a literature correlation. The accordance is acceptable for the ranges studied. Velocity profiles in significant regions are reported (drop nose, drop bottom and continuous phase liquid film). The influence of changing one dimensionless parameter alone was assessed. For small and large viscosity ratios, axisymmetric behavior is not a valid assumption.
    journal article Portugal Restricted access
  17. 9917
  18. 9918
    Cover Icon

    Does corruption boost or harm firms' performance in developing and emerging economies? A firm‐level study

    Publication
    In the last decade, a growing number of studies have addressed the ongoing debate about whether corruption sands or greases the wheels of business at the firm level. This study revisits this debate and proposes a comprehensive theoretical framework to test whether corruption harms or boosts firm performance, as well as the extent to which this relationship is mediated by the countries institutional settings, the size and strategic behaviour of the firms, and market competition. Based on a sample of 21,250 firms located in 117 emerging and developing countries, and resorting to instrumental variable (IV) estimations, three main results were found: (a) regardless of the proxy used for corruption and firm performance, the former clearly harms the latter; (b) corruption greases the wheels of business for African firms but it sands the wheels for firms in Latin America, the Caribbean, Eastern Europe, Central Asia, and Southern Asia; and (c) the negative impact of corruption on performance is mitigated for larger and exporting firms. (c) 2020 John Wiley & Sons Ltd
    journal article Portugal Restricted access
  19. 9919
  20. 9920